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针对长白山玄武岩区矿泉水资源开发利用程度不断增加的现状,为进一步保护及合理开发安图县矿泉水资源,根据野外实际调查数据,利用数理统计方法及水化学模拟等多种方法开展对安图县矿泉水形成机理的研究。首先绘制Piper三线图和离子浓度箱型图分析安图县矿泉水水化学特征;然后利用SPSS软件对特征组分偏硅酸展开相关性分析;运用离子比值分析法初步判定离子主要来源;再利用Phreeqc软件反向模拟研究区地下水三条路径的水岩交互作用;最后根据模拟结果综合分析安图县玄武岩区矿泉水的形成机理。结果显示,安图县玄武岩区天然矿泉水属弱碱性偏硅酸型矿泉水,偏硅酸含量介于28.8～62.4 mg/L之间,水化学类型以HCO3-Na型和HCO3-Na·Ca型为主。地下水发生了溶滤作用和Ca-Na离子交换作用。偏硅酸主要来源于长石和辉石的溶解,且偏硅酸含量沿径流途径增大。K+、Na+主要来源于硅酸盐矿物(钾长石、钠长石)和岩盐,Ca2+、Mg2+主要来源于碳酸盐矿物(方解石和白云石)。
Abstract：In view of the increasing development and utilization of mineral water resources in Changbai Mountain basalt area, in order to further protect and reasonably develop the mineral water resources in Antu County, according to the field survey data, the formation mechanism of mineral water in Antu County is studied by using mathematical statistics and hydrochemical analysis. Firstly, Piper three line diagram and ion concentration box diagram are drawn to analyze the chemical characteristics of mineral water in Antu County; after that, the correlation analysis of the characteristic component metasilicate is carried at by SPSS software; then, the main sources of ions are cletermined by ion ratio analysis; then, the water rock interaction of three paths of groundwater in the research area is simulated by using Phreeqc software; Finally, according to the simulation results, the formation mechanism of mineral water in Antu basalt area is comprehensively analyzed.The results of hydrochemical analysis show that the natural mineral water in basalt area of Antu County is weak alkali metasilicic acid mineral water, with the content of metasilicic acid between 28.8～62.4 mg/L, and the hydrochemical types are mainly HCO3-Na and HCO3-Na·Ca type. In addition to the filtration, Ca-Na ion exchange has taken place in groundwater. The results of ion ratio method and Phreeqc simulation show that metasilicic acid in groundwater mainly comes from the dissolution of feldspar and pyroxene, and the content of metasilicic acid increases along the runoff path. K+, Na+ mainly come from the dissolution of silicate minerals(K-feldspar, albite) and rock salt, while Ca2+, Mg2+ mainly come from the dissolution of carbonate minerals(calcite and dolomite).
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基本信息:
DOI：10.13928/j.cnki.wrahe.2021.10.014
中图分类号:P641.5
引用信息:
[1]朱洲洋,肖长来,梁秀娟,等.安图县玄武岩区偏硅酸型天然矿泉水水化学特征及形成机理[J],2021,52(10):146-156.DOI:10.13928/j.cnki.wrahe.2021.10.014.
基金信息:
国家自然科学基金项目(41572216);; 中国地质调查局项目(DD20190340);; 吉林省地质勘查基金项目(2018-13);; 省校共建计划专项(SXGJQY2017-6);; 陕西省重点研发计划(2017ZDCXL-SF-03-01-01)