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【目的】我国南方岩溶区广泛发育的岩溶洼地在降雨事件下通过落水洞形成集中灌入式补给,可在短时间内向岩溶地下河输入大量悬浮物及氮磷等面源污染物,从而引发显著的水质脉冲响应并增加地下水安全与生态风险。阐明集中补给驱动下多组分污染物的耦合迁移与转化机制,是岩溶地下水污染防控与水资源保护的关键科学问题。【方法】围绕“集中补给-水动力条件-悬浮物传输-氮磷迁移转化”的主线,系统综述了岩溶地下河水文动态特征及其水动力控制机制、悬浮物的来源与传输规律、以及氮磷在溶解态与颗粒吸附态之间的迁移转化过程及其影响机制的研究进展。【结果】现有研究表明,岩溶含水系统补给方式呈现多元化,水动力条件受补给状态调控并呈现显著时空异质性;水化学同位素与人工示踪等技术为识别产汇流过程和表征溶质运移过程提供了重要方法;悬浮物既可来源于坡面侵蚀等外源输入,也可由管道沉积物再悬浮产生,其通量受流速、紊流强度及管道发育等因素控制,并通过吸附-解吸、沉降-再悬浮及微生物附着等过程影响氮磷的形态分配与输出通量。【结论】当前研究仍面临管道-裂隙双重介质与非稳定流条件下多相耦合机制表征不足、多污染物竞争吸附及颗粒态二次释放过程认识不充分、以及氮磷循环与悬浮物迁移耦合的系统观测与模型验证缺乏等问题。未来研究需在降雨事件尺度上加强入口-管道-出口多点协同监测与示踪试验,结合高分辨率观测与耦合模拟,聚焦降雨驱动下多组分相互作用过程,进一步揭示悬浮物与氮磷的耦合迁移转化机制及其环境效应。
Abstract:[Objective]Karst depressions are widely developed in karst areas of southern China, generate concentrated recharge via sinkholes during rainfall events. This process can input large quantities of suspended solids and non-point source pollutants such as nitrogen and phosphorus into karst underground rivers in a short time, thereby inducing a significant pulse response of water quality and elevating the risks to groundwater security and ecological stability. Elucidating the coupled migration and transformation mechanisms of multi-component pollutants driven by concentrated recharge constitutes a key scientific issue for the prevention and control of karst groundwater pollution and the protection of water resources. [Methods]Following the main line of ‘concentrated recharge-hydrodynamic conditions-suspended solid transport-nitrogen and phosphorus migration and transformation’, the research progress was systematically reviewed on the hydrological dynamic characteristics of karst underground rivers and their hydrodynamic control mechanisms, the sources and transport laws of suspended solids, as well as the migration and transformation processes of nitrogen and phosphorus between the dissolved phase and particle-adsorbed phase and their influencing mechanisms. [Results]Existing studies have shown that the recharge patterns of karst aquifer systems exhibit diversification, and the hydrodynamic conditions are regulated by recharge status with significant spatiotemporal heterogeneity. Techniques such as hydrochemical isotopes and artificial tracers provide important methods for identifying runoff generation and confluence processes and characterizing solute transport processes. Suspended solids originate not only from external inputs such as slope erosion but also from the resuspension of conduit sediments, and their flux is controlled by factors including flow velocity, turbulence intensity and conduit development. Moreover, suspended solids affect the speciation distribution and export flux of nitrogen and phosphorus through processes such as adsorption-desorption, sedimentation-resuspension and microbial attachment.[Conclusion] Current research still faces several challenges: insufficient characterization of multiphase coupling mechanisms under the conditions of fissure-conduit dual media and unsteady flow, inadequate understanding of the competitive adsorption of multiple pollutants and the secondary release process of particulate pollutants, and lack of systematic observation and model validation for the coupling of nitrogen and phosphorus cycles with suspended solid migration. Future research needs to strengthen multi-point synergistic monitoring and tracer tests at recharge inlets, karst conduits and discharge outlets at the rainfall event scale. Combined with high-resolution observation and coupled simulation, it should focus on the interaction processes of multi-components driven by rainfall to further reveal the coupled migration and transformation mechanisms of suspended solids with nitrogen and phosphorus and their environmental effects.
[1] 袁道先,蒋勇军,沈立成,等. 现代岩溶学[M]. 北京:科学出版社,2016.
[2] LORETTE G, PEYRAUBE N, LASTENNET R, et al. Tracing water perturbation using NO_(3)~(-), DOC, particles size determination, and bacteria: a method development for karst aquifer water quality hazard assessment [J]. Science of The Total Environment, 2020, 725: 138512.
[3] VUCINIC L, O’CONNELL D, TEIXEIRA R, et al. Flow cytometry and fecal indicator bacteria analyses for fingerprinting microbial pollution in karst aquifer systems [J]. Water Resources Research, 2022, 58: e2021WR029840.
[4] YANG P, WANG Y, WU X, et al. Nitrate sources and biogeochemical processes in karst underground rivers impacted by different anthropogenic input characteristics [J]. Environmental Pollution, 2020, 265: 114835.
[5] GUO W, LI C, ZHENG T, et al. Decadal variations in nitrate isotopic composition reveal natural and anthropogenic impacts on nitrogen dynamics [J]. Journal of Hydrology, 2026, 664: 134438.
[6] FAN Z, TI C, YAN X, et al. Elucidating nitrate sources in a karst watershed: integrating isotope techniques, hydrochemical methods, and bayesian model [J]. Journal of Environmental Management, 2025, 392: 126793.
[7] ZHANG P, YUE F J, WANG X D, CHEN S N. Dynamic transformation and leaching processes of nitrogen in a karst agricultural soil under simulated rainfall conditions [J]. Journal of Contaminant Hydrology, 2025, 269: 104494.
[8] RICHTER D, GOEPPERT N, GOLDSCHEIDER N. New insights into particle transport in karst conduits using comparative tracer tests with natural sediments and solutes during low-flow and high-flow conditions [J]. Hydrological Processes, 2022, 36 (1): e14472.
[9] ZHAO W, LUO M, CHEN J, et al. Nitrogen response and transformation processes in karst water system using bacterial indicators [J]. Journal of Hydrology, 2025, 660: 133442.
[10] HU M, YU Z, GRIFFIS T J, et al. Combining stable isotopes and spatial stream network modelling to disentangle the roles of hydrological and biogeochemical processes on riverine nitrogen dynamics [J]. Water Research, 2025, 269: 122800.
[11] ?ALLI K ?, CHIOGNA G, BITTNER D, et al. Karst water resources in a changing world: review of solute transport modeling approaches [J]. Reviews of Geophysics, 2025, 63 (1): e2023RG000811.
[12] 顾昊晨,罗明明,周宏. 中国南方岩溶水系统氮素迁移机制研究进展[J/OL]. 水利水电技术 (中英文), 2026, 1-17[2026-01-26] (2026-06-03).https://link.cnki.net/urlid/10.1746.TV.20260123.1725.002.
[13] CHEN J, LUO M, WAN L, et al. Accumulation, conversion and storage of solute from sinkholes to karst spring under concenrated recharge conditions [J]. Journal of Hydrology, 2023, 620: 129396.
[14] HARTMANN A, GOLDSCHEIDER N, WAGENER T, et al. Karst water resources in a changing world: review of hydrological modeling approaches [J]. Reviews of Geophysics, 2014, 52: 218-242.
[15] 罗明明,周宏,陈植华. 香溪河流域岩溶水循环规律[M]. 北京:科学出版社,2018.
[16] 陈洪松,杨静,傅伟,等. 桂西北喀斯特峰丛不同土地利用方式坡面产流产沙特征[J]. 农业工程学报,2012, 28 (16): 121-126.
[17] PENG T, WANG S. Effects of land use, land cover and rainfall regimes on the surface runoff and soil loss on karst slopes in southwest china [J]. Catena, 2012, 90: 53-62.
[18] WANG S, FU Z, CHEN H, et al. Mechanisms of surface and subsurface runoff generation in subtropical soil-epikarst systems: implications of rainfall simulation experiments on karst slope [J]. Journal of Hydrology, 2020, 580: 124370.
[19] 康凤新,郑婷婷,冯亚伟,等. 北方岩溶区降水入渗补给系数及补给机制:以羊庄岩溶水系统为例[J]. 地质科技通报,2024, 43 (2): 268-282.
[20] 罗明明,周宏. 岩溶水文过程及其识别[M]. 武汉:中国地质大学出版社,2022.
[21] TEIXEIRA G M, PAULA R S, VELASQUEZ L N M, et al. Evaluation of recharge estimation methods applied to fissure and karst aquifers of the lagoa santa karst environmental protection area, brazil [J]. Hydrological Processes, 2023, 37: e14971.
[22] LIU F, JIANG G, WANG G, et al. Surface-subsurface hydrological processes of rainwater harvesting project in karst mountainous areas indicated by stable hydrogen and oxygen isotopes [J]. Science of The Total Environment, 2022, 831: 154924.
[23] RONCHETTI F, DEIANA M, LUGLI S, et al. Water isotope analyses and flow measurements for understanding the stream and meteoric recharge contributions to the poiano evaporite karst spring in the north apennines, italy [J]. Hydrogeology Journal, 2023, 31: 601-619.
[24] LUO M, CHEN Z, ZHOU H, et al. Hydrological response and thermal effect of karst springs linked to aquifer geometry and recharge processes [J]. Hydrogeology Journal, 2018, 26 (2): 629-639.
[25] ARONSON H S, CLARK C E, LAROWE D E, et al. Sulfur disproportionating microbial communities in a dynamic, microoxic-sulfidic karst system [J]. Geobiology, 2023, 21 (6): 791-803.
[26] MOHAMMADI Z, ILLMAN W A, FIELD M. Review of laboratory scale models of karst aquifers: approaches similitude and requirements [J]. Groundwater, 2021, 59 (2): 163-174.
[27] ZHAO X, CHANG Y, WU J, et al. Identifying transient storage model parameters in karst conduits using the normal-score ensemble smoother with multiple data assimilation [J]. Journal of Hydrology, 2024, 631: 130730.
[28] CHOLET C, CHARLIER J B, MOUSSA R, et al. Assessing lateral flows and solute transport during floods in a conduit-flow-dominated karst system using the inverse problem for the advection-diffusion equation [J]. Hydrology and Earth System Sciences, 2017, 21 (7): 3635-3653.
[29] YIN M, MA R, ZHANG Y, et al. A dual heterogeneous domain model for upscaling anomalous transport with multi-peaks in heterogeneous aquifers [J]. Water Resources Research, 2022, 58: e2021WR031128.
[30] AYDIN H, EKMEKCI M, SOYLU M E. Effects of sinuosity factor on hydrodynamic parameters estimation in karst systems: a dye tracer experiment from the beyyayla sinkhole (eskiehir turkey)[J]. Environmental Earth Sciences, 2014, 71 (9): 3921-3933.
[31] BAILLY-COMTE V, MARTIN J B, JOURDE H, et al. Water exchange and pressure transfer between conduits and matrix and their influence on hydrodynamics of two karst aquifers with sinking streams [J]. Journal of Hydrology, 2010, 386 (1-4): 55-66.
[32] RAVBAR N, BARBERA J A, PETRIC M, et al. The study of hydrodynamic behaviour of a complex karst system under low-flow conditions using natural and artificial tracers (the catchment of the unica river sw slovenia)[J]. Environmental Earth Sciences, 2012, 65 (8): 2259-2272.
[33] BINET S, JOIGNEAUX E, PAUWELS H, et al. Water exchange mixing and transient storage between a saturated karstic conduit and the surrounding aquifer: groundwater flow modeling and inputs from stable water isotopes [J]. Journal of Hydrology, 2017, 544: 278-289.
[34] RABAH A, MARCOUX M, LABAT D. Effects of geometry on artificial tracer dispersion in synthetic karst conduit networks [J]. Water, 2023, 15 (22): 3885.
[35] LUO M, ZHOU Z, CHEN J, et al. Identifying solute loss from karst conduit to fissures under concentrated recharge conditions [J]. Journal of Hydrology, 2025, 647: 132370.
[36] 杨平恒. 重庆青木关地下河系统的水文地球化学特征及悬浮颗粒物运移规律[D]. 重庆:西南大学,2010.
[37] VUILLEUMIER C, JEANNIN P Y, HESSENAUER M, et al. Hydraulics and turbidity generation in the milandre cave (switzerland)[J]. Water Resources Research, 2021, 57 (8): e2020WR029550.
[38] HERMAN E K, TORAN L, WHITE W B. Clastic sediment transport and storage in fluviokarst aquifers: an essential component of karst hydrogeology [J]. Carbonates and Evaporites, 2012, 27: 211-241.
[39] BETTEL L, FOX J, HUSIC A, et al. Sediment transport investigation in a karst aquifer hypothesizes controls on internal versus external sediment origin and saturation impact on hysteresis [J]. Journal of Hydrology, 2022, 613: 128391.
[40] NERANTAZAKI S D, GIANNAKIS G V, EFSTATHIOU D, et al. Modeling suspended sediment transport and assessing the impacts of climate change in a karstic mediterranean watershed [J]. Science of The Total Environment, 2015, 538: 288-297.
[41] GOLDSCHEIDER N, PRONK M, ZOPFI J. New insights into the transport of sediments and microorganisms in karst groundwater by continuous monitoring of particle-size distribution [J]. Geologia Croatica, 2010, 63 (2): 137-142.
[42] JUKIC D, DENIC-JUKIC V, KADIC A. Temporal and spatial characterization of sediment transport through a karst aquifer by means of time series analysis [J]. Journal of Hydrology, 2022, 609: 127753.
[43] MUELLER Y K, GOLDSCHEIDER N, EICHE E, et al. From cave to spring: understanding transport of suspended sediment particles in a fully phreatic karst conduit using particle analysis and geochemical methods [J]. Hydrological Processes, 2023, 37 (10): e14979.
[44] JUKIC D, DENIC-JUKIC V. An alternative approach to investigation of sediment transport through a karst aquifer [J]. Journal of Hydrology, 2023, 625: 130037.
[45] 杨平恒,刘子琦,贺秋芳. 降雨条件下岩溶泉水中悬浮颗粒物的运移特征及来源分析[J]. 环境科学,2012, 33 (10): 3376-3381.
[46] JAFARZADEH A, MATTA A, MOGHADAM S V, et al. Evaluation of stormwater runoff pollutant distributions combined with land-use information in a regional karst aquifer in texasusa [J]. Environmental Monitoring and Assessment, 2024, 196 (11): 1124.
[47] SHAO Y X, WANG Y X, XU X Q, et al. Occurrence and source apportionment of pahs in highly vulnerable karst system [J]. Science of The Total Environment, 2014, 490: 153-160.
[48] CELIK M, CALLI S S, KARAKAS Z S. The role of mineralogical studies in delineating the recharge area and groundwater circulation of susuz springs, central taurus belt, turkey [J]. Hydrogeology Journal, 2022, 30 (8): 2399-2415.
[49] HONIOUS S A S, HALE R L, GUILINGER J J, et al. Turbidity structures the controls of ecosystem metabolism and associated metabolic process domains along a 75-km segment of a semiarid stream [J]. Ecosystems, 2022, 25 (2): 422-440.
[50] SUN M W, WANG Z C, LI J H, et al. Interpretation of suspended sediment concentration-runoff hysteresis loops in two small karst watersheds [J]. Earth Surface Processes and Landforms, 2024, 49 (12): 3765-3778.
[51] 耿新新. 高原山地岩溶水系统的流动传输模式及水文过程模拟[D]. 北京:中国地质大学 (北京), 2022.
[52] 曹萌萌. 管道中悬浮物运移影响因素的实验及数值模拟研究[D]. 南京:南京大学,2018.
[53] GOEPPERT N, GOLDSCHEIDER N. Improved understanding of particle transport in karst groundwater using natural sediments as tracers [J]. Water Research, 2019, 166: 115045.
[54] PRONK M, GOLDSCHEIDER N, ZOPFI J. Particle-size distribution as indicator for fecal bacteria contamination of drinking water from karst springs [J]. Environmental Science & Technology, 2007, 41 (24): 8400-8405.
[55] VESPER D J, WHITE W B. Metal transport to karst springs during storm flow: an example from fort campbell kentucky/tennessee usa [J]. Journal of Hydrology, 2003, 276 (1-4): 20-36.
[56] 杨平恒,旷颖仑,袁文昊,等. 降雨条件下典型岩溶流域地下水中的物质运移[J]. 环境科学,2009, 30 (11): 3249-3255.
[57] RUGNER H, SCHWIENTEK M, BECKINGHAM B, et al. Turbidity as a proxy for total suspended solids (tss) and particle facilitated pollutant transport in catchments [J]. Environmental Earth Sciences, 2013, 69: 373-380.
[58] 韦丽丽. 岩溶地下河系统持久性有机污染物分布与迁移研究[D]. 重庆:西南大学,2011.
[59] AGUILERA R, MELACK J M. Concentration-discharge responses to storm events in coastal california watersheds [J]. Water Resources Research, 2018, 54 (1): 407-424.
[60] PAL S K, MASUM M M H, SALAUDDIN M, et al. Appraisal of stormwater-induced runoff quality influenced by site-specific land use patterns in the south-eastern region of bangladesh [J]. Environmental Science and Pollution Research, 2023, 30 (13): 36112-36126.
[61] BARAZA T, HASENMUELLER E A. Floods enhance the abundance and diversity of anthropogenic microparticles (including microplastics and treated cellulose) transported through karst systems [J]. Water Research, 2023, 242: 120204.
[62] FOX J T, ADAMS G, SHARUM M, et al. Passive sampling of bioavailable organic chemicals in perry county, missouri cave streams [J]. Environmental Science & Technology, 2010, 44 (23): 8835-8841.
[63] WALLACE C B, BURTON M G, HEFNER S G, et al. Effect of preceding rainfall on sediment, nutrients, and bacteria in runoff from biosolids and mineral fertilizer applied to a hayfield in a mountainous region [J]. Agricultural Water Management, 2013, 130: 113-118.
[64] LIU X, FU Z, ZHANG W, et al. Soluble carbon loss through multiple runoff components in the shallow subsurface of a karst hillslope: impact of critical zone structure and land use [J]. Catena, 2023, 222: 106868.
[65] ZHANG Z, CHEN X, CHENG Q, et al. Coupled hydrological and biogeochemical modelling of nitrogen transport in the karst critical zone [J]. Science of The Total Environment, 2020, 732: 138902.
[66] 朱晓锋,陈洪松,付智勇,等. 喀斯特灌丛坡地土壤-表层岩溶带产流及氮素流失特征[J]. 应用生态学报,2017, 28 (7): 2197-2206.
[67] 马丽娜. 岩溶坡地水-土-磷素流失过程及其控制因素[D]. 重庆:西南大学,2021.
[68] PRONK M, GOLDSCHEIDER N, ZOPFI J. Dynamics and interaction of organic carbon, turbidity and bacteria in a karst aquifer system [J]. Hydrogeology Journal, 2006, 14: 473-484.
[69] MENNING D, CARRAHER-STROSS W, GRAHAM E, et al. Aquifer discharge drives microbial community change in karst estuaries [J]. Estuaries and Coasts, 2018, 41: 430-443.
[70] 邹胜章,邓振平,梁彬,等. 岩溶水系统中微生物迁移机制[J]. 环境污染与防治,2010, 32 (10): 1-4.
[71] LIU X, YUE F J, WONG W W, et al. Unravelling nitrate transformation mechanisms in karst catchments through the coupling of high-frequency sensor data and machine learning [J]. Water Research, 2024, 267: 122507.
[72] KUTVONEN H, RAJALA P, CARPEN L, et al. Nitrate and ammonia as nitrogen sources for deep subsurface microorganisms [J]. Frontiers in Microbiology, 2015, 6: 1079.
[73] LI Q, CHENG X, LIU X, et al. Ammonia-oxidizing archaea adapted better to the dark, alkaline oligotrophic karst cave than their bacterial counterparts [J]. Frontiers in Microbiology, 2024, 15: 1377721.
[74] HE Z, ZHANG P, WU L, et al. Microbial functional gene diversity predicts groundwater contamination and ecosystem functioning [J]. mBio, 2018, 9 (1): e02435-17.
[75] CHEN X, PELTIER E, STURM B S M, et al. Nitrogen removal and nitrifying and denitrifying bacteria quantification in a stormwater bioretention system [J]. Water Research, 2013, 47 (4): 1691-1700.
[76] MEDRIANO C A, CHAN A, DE SOTTO R, et al. Different types of landuse influence soil physiochemical properties, the abundance of nitrifying bacteria, and microbial interactions in tropical urban soil [J]. Science of The Total Environment, 2023, 869: 161722.
[77] ZOU H, HE J, CHU Y, et al. Revealing discrepancies and drivers in the impact of lomefloxacin on groundwater denitrification throughout microbial community growth and succession [J]. Journal of Hazardous Materials, 2024, 465: 133139.
[78] GHODSZAD L, REYHANITABAR A, OUSTAN S, et al. Phosphorus sorption and desorption characteristics of soils as affected by biochar [J]. Soil and Tillage Research, 2022, 216: 105251.
[79] DUHAMEL S. The microbial phosphorus cycle in aquatic ecosystems [J]. Nature Reviews Microbiology, 2024: 1-17.
[80] SULLIVAN T P, GAO Y, REIMANN T. Nitrate transport in a karst aquifer: numerical model development and source evaluation [J]. Journal of Hydrology, 2019, 573: 432-448.
[81] ZHANG Z, CHEN X, LI S, et al. Linking nitrate dynamics to water age in underground conduit flows in a karst catchment [J]. Journal of Hydrology, 2021, 596: 125699.
[82] RUSJAN S, VIDMAR A. The role of seasonal and hydrological conditions in regulating dissolved inorganic nitrogen budgets in a forested catchment in sw slovenia [J]. Science of The Total Environment, 2017, 575: 1109-1118.
基本信息:
中图分类号:X523
引用信息:
[1]罗明明,谢蕊,顾昊晨,等.岩溶地下河悬浮物与氮磷耦合迁移研究进展[J].水利水电技术(中英文)().
基金信息:
广西重点研发计划项目(桂科AB24010016); 国家自然科学基金项目(42172276)
2026-06-04
2026-06-04
2026-06-04