程佳豪,姚天,胡晓农,支传顺,董玉龙,吴光伟,赵瑾

• 1:济南大学水利与环境学院
• 2:山东省国土空间生态修复中心
• 3:山东省海河淮河小清河流域水利管理服务中心

摘要(Abstract)：

【目的】为优化地下水水质监测方案，确定鲁西北平原地下水水质的主要控制因素，快速掌握地下水水质变化，【方法】基于2020年鲁西北平原地区浅层地下水水质数据，利用统计学软件、GIS软件对研究区水质情况进行描述性统计与空间信息差异化分析；基于熵权水质指数(EWQI)利用多元线性回归模型探讨能代表研究区地下水水质的化学指标。【结果】结果显示：鲁西北平原地下水水质趋于一个较为中等的状态，冲积海积平原咸水水文地质亚区与冲积平原咸淡水水文地质亚区水质较差，冲积洪积平原淡水水文地质亚区水质相对较好；EWQI模型指标优化后代表整个研究区地下水水质的水化学指标为TDS、Mn~(2+)、I~-、F~-和Al~(3+),指标优化后EWQI_(min)模型R~2和RMSE值分别为0.996和5.094,百分比误差PE为3.615%。【结论】结果表明：EWQI_(min)模型优选指标具有较好的代表性，可用作水质监测主要监控对象，为水质监测网优化调整及相关管理措施提供了参考。

关键词(KeyWords)： 地下水;水质评价;水化学特征;熵权水质指数;多元线性回归;EWQI_(min)评价指标优化

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金项目(42202277);; 济南市“新高校20条”引进创新团队项目(2021GXRC070);; 山东省地质灾害调查监测与治理“全省地下水水质监测网优化研究”(SDGP370000000202202003795)

作者(Author): 程佳豪,姚天,胡晓农,支传顺,董玉龙,吴光伟,赵瑾

DOI: 10.13928/j.cnki.wrahe.2024.04.013

参考文献(References)：

• [1] UDDIN M G,NASH S,RAHMAN A,et al.Assessing optimization techniques for improving water quality model [J].Journal of Cleaner Production,2023,385:135671.
• [2] DING F,ZHANG W,CHEN L,et al.Water quality assessment using optimized CWQII in Taihu Lake [J].Environmental Research,2022,214:113713.
• [3] 杨红遍，刘然，李炳华，等.引温济潮受水区地下水水文地球化学特征及水质变化趋势[J].南水北调与水利科技(中英文),2023,21(4):689-700.YANG H B,LIU R,LI B H,et al.Hydrogeochemistry characteristics and groundwater quality change trend in the “from Wenyu River to Chaobai River” water diversion area[J].South-to-North Water Transfers and Water Science & Technology,2023,21(4):689-700.
• [4] UDDIN M G,NASH S,OLBERT A I.A review of water quality index models and their use for assessing surface water quality [J].Ecological Indicators,2021,122:107218.
• [5] NOORI R,BERNDTSSON R,HOSSEINZADEH M,et al.A critical review on the application of the national sanitation foundation water quality index [J].Environmental Pollution,2019,244:575-587.
• [6] UDDIN M G,NASH S,RAHMAN A,et al.A comprehensive method for improvement of water quality index (WQI) models for coastal water quality assessment [J].Water Research,2022,219:118532.
• [7] NONG X,SHAO D,ZHONG H,et al.Evaluation of water quality in the South-to-North Water Diversion Project of China using the water quality index (WQI) method [J].Water Research,2020,178:115781.
• [8] GORGIJ A D,WU J,MOGHADAM A A.Groundwater quality ranking using the improved entropy TOPSIS method:A case study in Azarshahr plain aquifer,east Azerbaijan,Iran [J].Human and Ecological Risk Assessment:An International Journal,2019,25(1-2):176-190.
• [9] CHENG X,CHEN L,SUN R,et al.Land use changes and socio-economic development strongly deteriorate river ecosystem health in one of the largest basins in China [J].Science of the Total Environment,2018,616-617:376-385.
• [10] 刘子奇，仇付国，李红岩，等.华北平原某区农村供水水质与健康风险评估[J].环境化学，2021,40(7):2054-2063.LIU Ziqi,QIU Fuguo,LI Hongyan,et al.Evaluations of rural drinking water quality and health risk in the North China Plain[J].Environmental Chemistry,2021,40(7):2054-2063.
• [11] SUTADIAN A D,MUTTIL N,YILMAZ A G,et al.Development of river water quality indices:A review [J].Environmental Monitoring and Assessment,2016,188(1):58.
• [12] LI Z,YANG T,HUANG C-S,et al.An improved approach for water quality evaluation:TOPSIS-based informative weighting and ranking (TIWR) approach [J].Ecological Indicators,2018,89:356-364.
• [13] PEIYUE L,JIANHUA W,HUI Q.Groundwater quality assessment based on entropy weighted osculating value method [J].International Journal on Environmental Sciences,2010,1:621-630.
• [14] SUBBA RAO N,DAS R,GUGULOTHU S.Understanding the factors contributing to groundwater salinity in the coastal region of Andhra Pradesh,India [J].Journal of Contaminant Hydrology,2022,250:104053.
• [15] 陈思.重庆平行岭谷区地下水化学时空分布、形成机理与健康风险研究[D].武汉：中国地质大学环境学院，2022.CHENG Si.Temporal and spatial hydrochemical distribution,genetic mechanism and health risk of groundwater resource in the Chongqing parallel ridge and valley area[D].Wuhan:China University of Geosciences,2022.
• [16] NAFII A,LAMANE H,TALEB A,et al.An approach based on multivariate distribution and Gaussian copulas to predict groundwater quality using DNN models in a data scarce environment [J].MethodsX,2023,10:102034.
• [17] SINGHA S,PASUPULETI S,SINGHA S S,et al.Prediction of groundwater quality using efficient machine learning technique [J].Chemosphere,2021,276:130265.
• [18] MIA M Y,ISLAM A R M T,JANNAT J N,et al.Identifying factors affecting irrigation metrics in the Haor basin using integrated Shannon′s entropy,fuzzy logic and automatic linear model [J].Environmental Research,2023,226:115688.
• [19] 郑紫吟，储小东，徐金英，等.南昌市浅层地下水水质评价及监测指标优化[J].环境科学，2023,44(7):3846-3854.ZHENG Ziyin,CHU Xiaodong,XU Jinying,et al.Evaluation of shallow groundwater quality and optimization of monitoring indicators in Nanchang[J].Environmental Science,2023,44(7):3846-3854.
• [20] LI C,GAO Z,CHEN H,et al.Hydrochemical analysis and quality assessment of groundwater in southeast North China Plain using hydrochemical,entropy-weight water quality index,and GIS techniques [J].Environmental Earth Sciences,2021,80(16):523.
• [21] GAO Z,HAN C,YUAN S,et al.Assessment of the hydrochemistry,water quality,and human health risk of groundwater in the northwest of Nansi Lake Catchment,north China [J].Environmental Geochemistry and Health,2022,44(3):961-977.
• [22] 中华人民共和国国家质量监督检验检疫总局.地下水质量标准：GB/T 14848—2017 [S].北京：中国标准出版社，2018.General Administration of Quality Supervision.Inspection and Quarantine of the People′s Republic of China.Standard for groundwater quality:GB/T 14848—2017[S].Beijing:Standards Press of China,2018.
• [23] CHIDIAC S,EL NAJJAR P,OUAINI N,et al.A comprehensive review of water quality indices (WQIs):History,models,attempts and perspectives [J].Reviews in Environmental Science and Bio/Technology,2023,22(2):349-395.
• [24] 乔建华.海河流域河湖生态环境复苏管理与实践[J].水利发展研究，2023,23(12):9-13.QIAO Jianhua.Management and practice of ecological environment recovery in the Haihe River Basin[J].Water Resources Development Research,2023,23(12):9-13.
• [25] 齐璇璇，刘苏哲，张志胜，等.滨州市浅层地下水化学时空变化及成因分析[J].地球与环境，2022,50(5):733-743.QI Xuanxuan,LIU Suzhe,ZHANG Zhisheng,et al.Spatial-temporal variation of shallow groundwater chemistry in Binzhou City and its cause analysis [J].Earth and Environment,2022,50(5):733-743.
• [26] LIU Z,FENG S,ZHANGSONG A,et al.Long-term evolution of groundwater hydrochemistry and its influencing factors based on self-organizing map (SOM) [J].Ecological Indicators,2023,154:110697.
• [27] NAIK M R,MAHANTY B,SAHOO S K,et al.Assessment of groundwater geochemistry using multivariate water quality index and potential health risk in industrial belt of central Odisha,India [J].Environmental Pollution,2022,303:119161.
• [28] 徐雄，肖培平，孙艳亭，等.鲁西南黄河冲积平原地下水氟碘特征及成因分析[J].生态与农村环境学报，2020,36(2):186-192.XU Xiong,XIAO Peiping,SUN Yanting,et al.Study on the characteristics and physical causes of groundwater fluoride and Iodide over the Yellow River alluvial plain in the southwest of Shandong Province[J].Journal of Ecology and Rural Environment,2020,36(2):186-192.
• [29] ZHI C,HU B X,CHANG W,et al.Enrichment mechanism of fluoride and iodine in saline groundwater in the lower flood plain of the Yellow River,northern China [J].Journal of Hydrology,2023,621:129529.
• [30] WANG S,CHEN J,ZHANG S,et al.Hydrochemical evolution characteristics,controlling factors,and high nitrate hazards of shallow groundwater in a typical agricultural area of Nansi Lake Basin,North China [J].Environmental Research,2023,223:115430.
• [31] LIU J,PENG Y,LI C,et al.A characterization of groundwater fluoride,influencing factors and risk to human health in the southwest plain of Shandong Province,North China [J].Ecotoxicology and Environmental Safety,2021,207:111512.
• [32] 鲁孟胜，韩宝平，武凡，等.鲁西南地区高氟地下水特征及成因探讨[J].中国地质，2014,41(1):294-302.LU Mengsheng,HAN Baoping,WU Fan,et al.Discussion on the characteristics and causes of high fluoride groundwater in southwestern Shandong[J].China Geology,2014,41(1):294-302.
• [33] 刘楠，陈盟，高东东，等.德阳市平原区浅层地下水水化学特征与健康风险评价[J].环境科学，2024,45(4):2129-2141.LIU Nan,CHEN Meng,GAO Dongdong,et al.Hydrochemical characteristics and health risk assessment of shallow groundwater in the plain area of Deyang City [J].Environmental Science,2024,45(4):2129-2141.
• [34] 夏军.华北地区水循环与水资源安全：问题与挑战[J].地理科学进展，2002(6):517-526.XIA Jun.Water cycle and water resources security in north China:Issues and challenges [J].Advances in Geographical Sciences,2002(6):517-526.
• [35] 邢立亭，张凤娟，李常锁，等.鲁北平原浅层地下水水化学特征[J].灌溉排水学报，2015,34(6):90-94.XING Liting,ZHANG Fengjuan,LI Changsuo,et al.Hydro-chemical characteristics of shallow groundwater in the Shandong Plain [J].Journal of Irrigation and Drainage,2015,34(6):90-94.
• [36] 刘中业，杨丽芝，张涛，等.鲁北平原一多年排污河渠对两侧浅层地下水水质的影响分析[J].地下水，2010,32(4):47-50.LIU Zhongye,YANG Lizhi,ZHANG Tao,et al.Analysis of the impact of a multi-year sewage drainage channel in the Shandong Plain on the quality of shallow groundwater on both sides [J].Groundwater,2010,32(4):47-50.
• [37] 刘中业，杨丽芝，祁晓凡，等.鲁北平原浅层地下水中砷的来源探析[J].山东国土资源，2013,29(6):29-33.LIU Zhongye,YANG Lizhi,QI Xiaofan,et al.Analysis of the sources of arsenic in shallow groundwater in the Shandong Plain[J].Shandong Land and Resources,2013,29(6):29-33.